darkmedian
Try:
Holding buttons 1&2 from beginning of connection until application executes (1 Blue Led at base remote lights up). I need to do this every now and then (I think the connection drops between connection and application execution) Why don't know?, Just works!
Failing that do diagnose try:
a) Connecting as above
b) Run Jason Smiths
http://jasonlpsmith.googlepages.com/ or other totally different app from Johnny's Wiimote hack apps.
Given your picture shows Wiimote connected (the yellow dotted line, no connection, no line) if app works will confirm a problem with software.
benpaddlejones