I built and IR array with 96 IR LEDs. The LEDs themselved show up just fine when I put them in front of the Wiimote. But I don't think that they were powerful enough to send the reflection back. I've been checking the LED status with my Canon PowerShot SD 1000, which can see the LED's just fine, but wasn't picking up very much in terms of IR reflection.
I was using High Power Infrared Emitting Diodes (Vishay model TSAL6400) at a 940nm wavelength and a 25 degree angle of intensity.
As a test, I checked to see if I could get a good reflection by shining my mini-Maglite forward and video recording the reflective tape on the finger movements. That worked great... my fingers showed up bright and clear with the lights off. I'm going to try using a high-powered IR spotlight(the kind used for nightvision illumination).
I'll let you know how that turns out, but I hope that a post about what didn't work will help out some.